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Ass. Lect. Mahmoud basyouni :: Publications: |
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| Title: | Synthesis, Characterization, and Optical Properties of Carbazole-
Functionalized Poly(norbornene-dicarboximide) by ROMP |
| Authors: | Mahmoud Z. Basyouni, Mohammed F. Radwan, Mohamed E. Abdu, Andrew M. Spring |
| Year: | 2024 |
| Keywords: | Organic Light-Emitting Diodes; Ring Opening Metathesis Polymerization; Grubbs Catalyst; Carbazole-Pendant Monomer |
| Journal: | EVERGREEN |
| Volume: | 11 |
| Issue: | 01 |
| Pages: | 207-213 |
| Publisher: | Joint Journal of Novel Carbon Resource Sciences & Green Asia Strategy |
| Local/International: | International |
| Paper Link: | Not Available |
| Full paper | Mahmoud basyouni_pp207-213.pdf |
| Supplementary materials | Not Available |
| Abstract: |
A novel norbornene-dicarboximide monomer functionalized with carbazole was synthesized and effectively polymerized using the Grubbs 3rd generation initiator. Extensive characterization through NMR, GPC, FT-IR, DSC, and UV-vis spectroscopy confirmed the polymer's characteristics. The polymer demonstrated the anticipated nearly 1:1 vinylene cis-trans microstructure, possessing a molecular weight of 26800 g/mol and a polydispersity index of 1.11. Its glass transition temperature, as determined by DSC, was 117 °C. UV-vis analysis confirmed the presence of the polymer-bound carbazole group, |
